Photocatalytic removal of gaseous nitrogen oxides using WO 3 /TiO 2 particles under visible light irradiation: Effect of surface modification

• Published in: Chemosphere (Oxford) 2017-09, Vol.182, p.539-546
• Main Authors: Mendoza, Joseph Albert, Lee, Dong Hoon, Kang, Joo-Hyon
• Format: Article
• Language: English
• Subjects: Light; Nitrous Oxide - chemistry; Oxides - chemistry; Photolysis; Titanium - chemistry; Tungsten - chemistry
• ISSN: 0045-6535; 1879-1298
• DOI: 10.1016/j.chemosphere.2017.05.069

Photocatalytic nanoparticles have been receiving considerable attention for their potential use in many environmental management applications, including urban air quality control. This paper investigates the performance of surface modified WO /TiO composite particles in removing gaseous nitrogen oxides (NO ) under visible light irradiation. The WO /TiO composite particles were synthesized using a modified wet chemical method with different concentrations of NaOH solution used as a surface modification agent for the host TiO particles. The NO removal efficiency of the WO /TiO particles was evaluated using a lab-scale continuous gas flow photo-reactor with a gas contact time of 1 min. Results showed that surface modification using NaOH can enhance the photocatalytic activity of the WO /TiO particles. The NO removal efficiency of the surface modified WO /TiO was greater than 90%, while that of WO /TiO particles prepared by the conventional wet chemical method was ∼75%. The enhanced removal efficiency might be attributed to the formation of oxygen vacancies on the TiO surface, providing sites for WO particles to effectively bind with TiO . However, excess amount of NaOH >3 M deteriorated the photocatalytic performance due to the increased agglomeration of the host TiO particles.