Specific adsorption of barbituric acid on ferric (III) and nickel (II) oxides

The dependence of NiO and Fe 2O 3 ζ-potential was investigated in the barbituric acid solutions (10 −4 mol/l) as a function of pH by microelectrophoresis method. Shifting of pH IEP (the isoelectric point or IER) towards the acid zone for NiO and Fe 2O 3 in the solutions of barbituric acid (BA) in co...

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Bibliographic Details
Published in:Colloids and surfaces. A, Physicochemical and engineering aspects Physicochemical and engineering aspects, 2004-05, Vol.239 (1), p.19-24
Main Authors: Dmitrieva, I.B, Prokopovich, P.P, Tikhomolova, K.P, Starov, V.M
Format: Article
Language:English
Subjects:
Barbituric acid
Ferric (III) oxide
Microelectrophoresis
Nickel (II) oxide
Specific adsorption
Surface complexation
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Summary:The dependence of NiO and Fe 2O 3 ζ-potential was investigated in the barbituric acid solutions (10 −4 mol/l) as a function of pH by microelectrophoresis method. Shifting of pH IEP (the isoelectric point or IER) towards the acid zone for NiO and Fe 2O 3 in the solutions of barbituric acid (BA) in comparison with HCl shows the presence of the specific adsorption of the anion forms of BA. The complexation process of Ni(II) and Fe(III) ions with BA in the solution and on the surface of their oxides was examined by methods of conductometry and spectrophotometry. It was determined that nickel (II) and ferric (III) ions form complexes with BA both in solution and on the surface of their oxides.
ISSN:0927-7757
1873-4359
DOI:10.1016/j.colsurfa.2003.12.033