Increasing particle concentration enhances particle penetration depth but slows down liquid imbibition in thin fibrous filters

• Published in: Colloids and surfaces. A, Physicochemical and engineering aspects Physicochemical and engineering aspects, 2024-03, Vol.684, p.133146, Article 133146
• Main Authors: Nicasy, R.J.K., Barquero, A., Huinink, H.P., Erich, S.J.F., Adan, O.C.G., Tomozeiu, N., Mansouri, H., Scheerder, J.
• Format: Article
• Language: English
• Subjects: Capillarity; Filter membrane; Iron oxide nanoparticles; NMR; SEM
• ISSN: 0927-7757; 1873-4359
• DOI: 10.1016/j.colsurfa.2024.133146

The transport of particles within thin, porous media is a complex process which received growing attention due to its applications in filtration, printing and microfluidics devices. The effect of particles on liquid imbibition and particle clogging can reduce the performance and lifetime of these applications. However, these processes are still not clearly understood and are challenging to investigate. The goal of this study is to increase our understanding about the effect of particle concentration on the imbibition process in thin fibrous membrane filters. In this study, an Ultra-Fast Imaging NMR method is used to study the particle penetration inside nylon membrane filters for particle suspensions with varying particle concentrations (C0). The measurements revealed that increasing the particle concentration increases the particle penetration depth S(t) as governed by a Langmuir isotherm given by S(t)=l(t)(1+κC0)/1+κ(C0+Cb,m), with Cb,m the bound particles and κ the binding constant. Secondly, in droplet penetration, particles slow down liquid penetration in a Darcy like manner where effect on viscosity (η) and surface tension (σ) determine the penetration speed rather than changes within permeability (K0). The final liquid front (l), scaled according to l2∝σt/η. The particle penetration depths were verified using scanning electron microscopy images. [Display omitted]