Pilot-scale evaluation of forward osmosis membranes for volume reduction of industrial wastewater

• Published in: Desalination 2022-06, Vol.531, p.115689, Article 115689
• Main Authors: Minier-Matar, Joel, Al-Maas, Mashael, Hussain, Altaf, Nasser, Mustafa S., Adham, Samer
• Format: Article
• Language: English
• Subjects: Commercial modules; Full-scale; Natural osmosis; Oil and gas; Osmotic concentration; Wastewater treatment
• ISSN: 0011-9164; 1873-4464
• DOI: 10.1016/j.desal.2022.115689

Water treatment is a key aspect for the sustainable management of oil & gas operations. Osmotic concentration (OC) is an advanced water treatment process, adapted from forward osmosis (FO), that does not require water recovery from the draw solution. In this study, two commercial hollow fiber FO membranes [Module 1, cellulose triacetate (CTA) and Module 2, thin film composite (TFC)] were evaluated at pilot scale using actual process water obtained from a gas production facility. The evaluation focused on assessing the membrane productivity, fouling potential and chemical cleaning efficiency while normalizing the performance using a theoretical model that account for the variability of the operating conditions. Performance tests showed that Module 2 has a higher flux compared to Module 1, 9.9 L/m2·h vs 1.7 L/m2·h; and lower specific reverse solute flux (RSF) for most of the ions. Additionally, Module 1 benchmark experiment showed a 13% flux loss attributed to inorganic fouling (calcium phosphate precipitation) while the flux loss in Module 2 was