Synthesis and characterization of new perylenediimide derivatives: Promising low-cost electron transport materials for perovskite solar cells

• Published in: Dyes and pigments 2024-12, Vol.231, p.112427, Article 112427
• Main Authors: Bizyaeva, Anastasia A., Akbulatov, Azat F., Ozerova, Victoria V., Emelianov, Nikita A., Buyanovskaya, Anastasiya G., Frolova, Lyubov A., Troshin, Pavel A., Kuklin, Sergey A.
• Format: Article
• Language: English
• ISSN: 0143-7208
• DOI: 10.1016/j.dyepig.2024.112427

In organic-inorganic perovskite solar cells (PSCs), the electron transport layer (ETL) plays a crucial role providing efficient electron extraction and transport required for achieving high device performance. Compared to traditional fullerene-based electron-transport materials (ETMs), non-fullerene small molecules have attracted much attention due to their tunable optoelectronic properties, lower cost, and much higher stability. In this work, we synthesized and characterized four perylenediimide (PDI) derivatives and investigated their optoelectronic properties in the context of application as ETMs for PSCs. To establish the compatibility of PDI films with perovskite absorber material, the surface properties of Cs0.12FA0.88PbI3/PDI bilayer stacks were studied using contact angle and infrared scattering scanning near-field microscopy methods. A study of the photochemical stability of these bilayer stacks showed that coating the perovskite film with a layer of PDI improves its tolerance with respect to light. Utilizing these molecules as ETMs in the inverted p-i-n PSCs delivered light power conversion efficiencies ranging from 11.1 % to 15.4 %, thus indicating the considerable effect of the PDI derivative molecular structure on the photovoltaic properties. Further development of this research direction may lead to the rational design of advanced PDI-based electron transport materials for efficient and stable PSCs. [Display omitted] •New PDI derivatives with sulfur, selenium, and amine bridges were synthesized.•PDI films quality and morphology strongly depends on their molecular structure.•PDI derivatives were explored as ETL in p-i-n PSCs.•Relationship between the ETL films uniformity and performance in PSCs was established.•PSCs using PDI derivative with selenium bridge showed the highest efficiency.