Seeking a reliable electrode for the monitoring of the hydrogen peroxide reduction in the presence of antioxidants

•Electrodes based on carbon (graphite and glassy-carbon) covered by conducting polymers and Pt nanoparticles have been prepared and studied.•Conducting polymers were PANI (polyaniline) and PNR (Poly-neutral red), being the GCE/PNR/Pt electrode the most reliable for the monitorization of H2O2 reducti...

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Bibliographic Details
Published in:Electrochimica acta 2015-07, Vol.171, p.150-155
Main Authors: Rivas, P., Rodríguez Mellado, J.M.
Format: Article
Language:English
Subjects:
antioxidants
electrocatalysis
Hydrogen peroxide
poly-neutral red
polyaniline
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Summary:•Electrodes based on carbon (graphite and glassy-carbon) covered by conducting polymers and Pt nanoparticles have been prepared and studied.•Conducting polymers were PANI (polyaniline) and PNR (Poly-neutral red), being the GCE/PNR/Pt electrode the most reliable for the monitorization of H2O2 reduction.•The GCE/PNR/Pt electrode can be used to assess the scavenging ability of antioxidants, substituting the mercury electrode. In this work are proposed electrodes modified with conductive polymers and metallic nanoparticles for the determination of antioxidant capacity, with the aim to avoid the use of mercury electrodes. Carbon materials as pure graphite and glassy carbon, covered with polyaniline and poly-neutral red, were used after deposition of platinum on the polymer surface. The best electrode found, glassy carbon+poly-neutral red+Pt, showed a clear signal of H2O2 reduction, being stable (more than 5 months) and reproducible. This electrode can assess the scavenging ability of ascorbic acid in a similar way as reported for mercury electrodes, with the advantage of the avoiding the use of mercury.
ISSN:0013-4686
1873-3859
DOI:10.1016/j.electacta.2015.05.026