Loading…
Unveiling the surface dominated capacitive properties in flexible ternary polyaniline/NiFe2O4/reduced graphene oxide nanocomposites hydrogel electrode for supercapacitor applications
•3D ternary polyaniline/NiFe2O4/rGO (PNFG) hydrogels on carbon cloth were synthesized.•PNFG on carbon cloth act as binder-free flexible electrodes for supercapacitors.•Maximum specific capacitance of 1134.28 F/g at a current density of 1 A/g.•The symmetric supercapacitor cell delivered Es of 19.29 W...
Saved in:
Published in: | Electrochimica acta 2022-12, Vol.434, p.141324, Article 141324 |
---|---|
Main Authors: | , , , , , , , , |
Format: | Article |
Language: | English |
Subjects: | |
Citations: | Items that this one cites Items that cite this one |
Online Access: | Get full text |
Tags: |
Add Tag
No Tags, Be the first to tag this record!
|
Summary: | •3D ternary polyaniline/NiFe2O4/rGO (PNFG) hydrogels on carbon cloth were synthesized.•PNFG on carbon cloth act as binder-free flexible electrodes for supercapacitors.•Maximum specific capacitance of 1134.28 F/g at a current density of 1 A/g.•The symmetric supercapacitor cell delivered Es of 19.29 Wh/kg and Ps of 0.61 kW/kg.•Performance depends on surface-controlled and diffusion-controlled mechanism.
The 3D ternary nanocomposites hydrogel have been effectively fabricated on carbon cloth using a two-step synthesis approach. Nickel ferrite nanoparticles (NiFe2O4) prepared by template method have been dispersed onto/within rGO nanosheets leading to the formation of NiFe2O4/rGO (NFG) nanocomposites. Afterward, polyaniline hydrogel has been polymerized on NFG nanosheets to prepare ternary polyaniline/NiFe2O4/rGO hydrogel (PNFG) nanocomposites on carbon cloth that can be further utilized as a binder-free supercapacitor electrode. The resulting 3D ternary nanocomposites hydrogel achieved maximum specific capacitance of 1134.28 F/g at a current density of 1 A/g and 76.46 % of capacitive retention at 10 A/g. The supercapacitor electrode exhibited outstanding rate capability and superior cyclic stability up to 5000 successive cycles. In addition, the symmetric supercapacitor cell delivered 0.61 kW/kg of specific power and 19.29 Wh/kg of specific energy. The excellent electrochemical characteristics of PNFG is ascribed to its well-designed 3D microstructure and the synergistic effect created by the capacitive mechanism due to electric double layer capacitance (EDLC) and pseudocapacitance (surface redox reactions) as well as diffusion-controlled mechanism (faradaic redox reactions). It has been revealed that the overall electrode reaction is dominated by surface-controlled processes, with a small contribution from diffusion-controlled faradaic processes.
[Display omitted] |
---|---|
ISSN: | 0013-4686 1873-3859 |
DOI: | 10.1016/j.electacta.2022.141324 |