Self-supported Mo-doped TiO2 electrode for ambient electrocatalytic nitrogen oxidation

• Published in: Electrochimica acta 2022-12, Vol.435, p.141333, Article 141333
• Main Authors: Yu, Meng, Fan, Guilan, Liu, Jiuding, Xu, Wence, Li, Jinhan, Cheng, Fangyi
• Format: Article
• Language: English
• Subjects: Electrochemical nitrogen oxidation; Mo-doped TiO2; N2 fixation; Nitrate synthesis; Self-supported electrode
• ISSN: 0013-4686; 1873-3859
• DOI: 10.1016/j.electacta.2022.141333

Electrocatalytic nitrogen oxidation reaction (NOR) provides an eco-friendly pathway for ambient N2 fixation and nitrate/nitric acid synthesis but is plagued by sluggish kinetics due to the weak adsorption of N2 molecules and cleavage of NN triple bonds. Herein, a self-supported Mo-doped TiO2 electrode prepared by one-step hydrothermal method is reported for efficient nitrogen oxidation. Electrochemical measurements and spectroscopy investigations reveal that the inert TiO2 is effectively triggered by Mo substitution in terms of enhanced N2 adsorption and activation. As further confirmed by density function theory calculations, the incorporation of Mo reduces the barrier of the rate-determining step and provides an energetically favorable NOR pathway compared to pristine rutile TiO2. Electrochemical results show that Mo-doped TiO2 electrode achieves a nitrate yield of 5.44 μg h−1 mgcat−1 (or 8.77 ± 0.39 nmol h−1 cm−2) with a Faradaic efficiency of 2.88%. The formation of nitrate from N2 under positive bias is further demonstrated by in situ ultraviolet-visible spectrophotometry. This work provides experimental and theoretical evidences that Mo doping can stimulate the stable yet electrocatalytically inert Ti-based oxide toward NOR via promoting active sites formation and lowering activation energy barriers.