Superior catalytic effect of nanocrystalline big-cube Zr2Ni metastable phase for improving the hydrogen sorption/desorption kinetics and cyclability of MgH2 powders

• Published in: Energy (Oxford) 2015-11, Vol.91, p.274-282
• Main Authors: El-Eskandarany, M. Sherif, Al-Matrouk, H., Shaban, Ehab, Al-Duweesh, Ahmed
• Format: Article
• Language: English
• Subjects: Cycle-life-time; Hydrogenation/dehydrogenation; Mechanical milling; Metal hydrides; Reactive ball milling; Zr alloys
• ISSN: 0360-5442
• DOI: 10.1016/j.energy.2015.07.135

Reactive ball milling was employed to synthesize nanocrystalline MgH2 powders using a high-energy ball milling of pure Mg powders under 50 bar of a hydrogen gas atmosphere. The end-product of MgH2 powders obtained after 200 h of a continuous reactive ball milling time composed of fine grains (∼7 nm in diameter) of γ and β phases. A new catalytic agent of big-cube Zr2Ni nanocrystalline phase, which is proposed in the present study for improving the hydrogenation/dehydrogenation kinetics of MgH2 powders, was obtained upon high-energy ball milling of tetragonal-Zr2Ni powders for 150 h. The as-ball milled Zr2Ni powders consisted of ultrafine grains with an average grain size of 6 nm in diameter. The as-prepared MgH2 powders were mechanically doped with 10 wt% of big-cube Zr2Ni powders for 50 h, using high-energy ball mill under a hydrogen gas atmosphere for 50 h. The powders obtained after 50 h of milling enjoyed homogeneous morphology and uniform composition close to the starting nominal composition. Moreover, this binary nanocomposite system possessed superior hydrogenation/dehydrogenation kinetics at 250 °C, as suggested by the short time required to absorb and desorb 5.1 wt% H2 within 100 s and 613 s, respectively. At this temperature, the synthesized nanocomposite powders possessed excellent absorption/desorption cyclability of 2546 complete cycles within 1250 h. However, a minor degradation (∼0.5 wt% H2) in the hydrogen storage capacity was observed between 300 h and 2546 h of the cycle-life-time. This slight degradation took place due to the grain growth came off in the Mg/Zr2Ni grains. •Room-temperature synthesizing of nanocomposite MgH2/10wt% Zr2Ni, using high-energy ball milling.•Effect of metastable big-cube Zr2Ni nanocatalysts on the hydrogenation/dehydrogenation kinetics and cycle-life-time of MgH2.•Effect of Mg/Zr2Ni grain growth on the hydrogenation/dehydrogenation cyclability of MgH2.