Influence of the morphology of barium sulfate nanofibers and nanospheres on the physical properties of polyurethane nanocomposites

• Published in: European polymer journal 2012-04, Vol.48 (4), p.670-676
• Main Authors: Romero-Ibarra, I.C., Bonilla-Blancas, E., Sánchez-Solís, A., Manero, O.
• Format: Article
• Language: English
• Subjects: Applied sciences; Barium sulfate; Composites; Exact sciences and technology; Forms of application and semi-finished materials; Nanocomposites; Nanofiber; Nanoparticles; Polymer industry, paints, wood; Polyurethane; Radio-opacity; Technology of polymers
• ISSN: 0014-3057; 1873-1945
• DOI: 10.1016/j.eurpolymj.2012.01.001

[Display omitted] ► Barium sulfate/polyurethane nanocomposites were prepared by melt extrusion. ► Morphology of nanoparticles (spherical and fibers) modified the rheological behavior. ► Convenient levels of radio-opacity were found maintaining the mechanical properties. ► BaSO4 nanoparticles do not diminish the transparency of the polyurethane matrix. Barium sulfate spherical agglomerates and fibers in the nanometric size range were used to prepare polyurethane (PU) nanocomposites (with 1wt.% concentration) via melt extrusion. A detailed analysis on the effect of the morphology of the barium sulfate phase upon the mechanical, rheological and optical properties was carried out. Results show that the inclusion of the dispersed phase (with various morphologies and sizes) in the polymer matrix does not decrease the polymer mechanical properties, as is observed when particles in the micrometric size range are included. Rheological studies show that the nanocomposite containing spherical particles presents a slightly higher shear viscosity than that of the polymer matrix, in contrast to the nano-fibers viscosity which presents lower values. This is reflected in the effect of the particle morphology on the processability of the material; in contrast, the morphology has no effect on the radio-opacity of the samples. The structure and dispersion of the particles were analyzed using scanning and transmission electron microscopy. The sample with 1wt.% nanofibers presents better processability than the system with spherical agglomerates maintaining the X-ray opacity properties.