Comparing the effects of CH4, CO2, and N2 injection on asphaltene precipitation and deposition at reservoir condition: A visual and modeling study

• Published in: Fuel (Guildford) 2018-04, Vol.217, p.633-641
• Main Authors: Zanganeh, Peyman, Dashti, Hossein, Ayatollahi, Shahab
• Format: Article
• Language: English
• Subjects: Asphaltene precipitation; Carbon dioxide injection; Enhanced oil recovery; Methane injection; Nitrogen injection
• ISSN: 0016-2361; 1873-7153
• DOI: 10.1016/j.fuel.2018.01.005

[Display omitted] •As the pressure increases, the amount of asphaltene deposition increases too.•CO2- and CH4-EOR resulted in more deposition comparing to the natural depletion.•No deposition increment was noticed during the N2 injection process.•The CO2 injection causes more asphaltene deposition compared to CH4. Enhanced Oil Recovery (EOR) through various methodologies has been an active research for many years seeking efficient methods to increase the crude oil recovery efficiency from oil reservoirs. Among different gas injection scenarios, carbon dioxide (CO2), natural gas (mainly methane (CH4)) and nitrogen (N2) injection are considered as promising EOR agents. Asphaltene precipitation and deposition during EOR methods cause severe problems, which affect the recovery efficiency and increase the cost of the incremental oil production. This study is aimed to investigate the effects of CH4 and N2 injection compared with CO2 injection on asphaltene precipitation and deposition. The different mole percent of the mentioned gases were introduced into the high-pressure cell, then the amount of precipitated asphaltene was measured at the reservoir condition. The evolution of asphaltene deposition was monitored through a high-resolution microscope. Moreover, Image processing software was utilized to check the amount of deposited asphaltene and its size distribution under different conditions. The most apparent finding to emerge from this study is that both CO2 and natural gas increase the amount of precipitated asphaltene whereas the nitrogen as an inert gas has no considerable effect on the amount of precipitated asphaltene. According to the results, the increment of precipitated asphaltene by CO2 is much higher than natural gas. Further, the thermodynamic solid model used in this study reasonably predicted the trend of asphaltene precipitation process for the mentioned EOR scenarios.