Recyclable NiMnOx/NaF catalysts: Hydrogen generation via steam reforming of formaldehyde

• Published in: Fuel (Guildford) 2023-12, Vol.354, p.129311, Article 129311
• Main Authors: Hu, Yongji, He, Weiyi, Shen, Yuesong
• Format: Article
• Language: English
• Subjects: Formaldehyde; Hydrogen generation; Recyclable NiMnOx/NaF catalyst; Steam reforming; Surface reaction
• ISSN: 0016-2361; 1873-7153
• DOI: 10.1016/j.fuel.2023.129311

[Display omitted] •NiMnOx/NaF efficiently steam reforming formaldehyde to produce hydrogen.•Recycled NiMnOx/NaF was restored to the level of the initial fresh sample.•Steam reforming formaldehyde over NiMnOx/NaF is a fast surface reaction.•Oxidation of formaldehyde to formic acid is the rate-determine step.•Doping of Mn effectively improved stability of NiMnOx/NaF. In this paper, a low-cost and efficient NiMnOx/NaF catalyst that can be recycled for re-preparation was developed by sol–gel method for formaldehyde steam reforming to produce hydrogen, aiming at the high cost of commercial reforming catalyst and the difficulty of recycling after deactivation and abandonment. Results showed that the NiMnOx/NaF catalyst could efficiently steam reforming formaldehyde to produce hydrogen. Among them, the catalyst with 5 wt% NiMnOx had better hydrogen production performance, achieving 100% hydrogen yield, 100% formaldehyde conversion and 100% carbon balance from 500 to 600 ℃. Moreover, 5%-NiMnOx/NaF catalyst exhibited excellent stability at 500 ℃ for 28 h and the hydrogen production performance of the recycled catalyst was restored to the level of the initial fresh sample. Combining analysis of FE-SEM, N2 adsorption/desorption, XRD, H2-TPR, in situ DRIFTS, XPS, and DFT calculations, it was found that the surface micro-structure of the NaF carrier was dense, and the specific surface area of the NiMnOx/NaF catalyst was very small, breaking through the limitation of low specific surface area catalysts that cannot obtain high-quality catalytic activity. Its steam reforming of formaldehyde to produce hydrogen was a fast surface reaction process. Ni and Mn species combined with NaF to form the Na0.67Ni0.33Mn0.67O2 phase, and F atom had a strong induction effect on Ni atom, which was conducive to weakening the Ni-O bond, thus improving the low-temperature redox performance of Ni2+. In the process of reforming formaldehyde to produce hydrogen, the NiMnOx/NaF catalyst could quickly adsorb and activate formaldehyde and H2O molecules, and promoted the formation of formate intermediates through the adsorbed hydroxyl groups on the surface, and then rapidly produced H2 and CO2.