Influence mechanisms of torrefaction on syngas production from bio-waste molten salt thermal treatment

• Published in: Fuel (Guildford) 2024-05, Vol.363, p.130965, Article 130965
• Main Authors: Liu, Yuhao, Zhang, Junwei, Hu, Hongyun, Dai, Qiqi, Zou, Chan, Cao, Chengyang, Zhao, Yongchun, Li, Aijun
• Format: Article
• Language: English
• Subjects: Bio-waste; Molten salt thermal treatment; Nitrate; Syngas; Torrefaction
• ISSN: 0016-2361
• DOI: 10.1016/j.fuel.2024.130965

[Display omitted] •Torrefaction promotes higher gas yield from bio-wastes in molten salts.•The elevation of lignin in the torrefied bio-wastes greatly enhances the CO yield.•Anions in the molten salt are more involved in the torrefied bio-wastes reaction.•Increase in lignin content and decrease in oxygen-containing groups delay reaction.•Sugarcane bagasse is highly graphitised after torrefaction at 280 ℃ and hardly react. The production of high-value syngas from bio-wastes through thermal conversion is a promising way to achieve carbon neutrality. In order to reduce the cost of the process, molten salt thermal treatment has been used for bio-wastes syngas production. Moreover, the removal of oxygen and water induced by torrefaction can effectively enhance the energy density of biomass, and the effect of these changes on the quality of syngas was widely investigated. This study proposed to torrefy bio-wastes and then produce syngas in molten NaNO3-NaNO2-KNO3 at 300 ℃. Results showed that the evaluation indices of syngas were improved, while the cold gas efficiency reached 44.02 % for beech wood torrefied at 280 ℃, and the syngas quality is equivalent to the products obtained by gasification of bio-wastes. The gas yield of the torrefied bio-wastes was increased by 8.08–45.23 % compared to the raw bio-wastes. Na+ and K+ in the molten salt catalyzed the cracking of propyl chains and ring opening of aromatic rings in lignin, resulting in a prominent enhancement in CO yield. Meanwhile, torrefaction could change the solid structure, leading to a delay in gas production, and torrefaction could also increase graphitization degree of char (C–C/C = C up to 50.72 % for SB-280), thus preventing the reaction proceeding. This study provided a new approach to enhance the content and quality of syngas from bio-wastes at low temperatures.