The regulation of dislocation and precipitated phase improving hydrogen embrittlement resistance of pipeline steel in high pressure hydrogen environment

• Published in: International journal of fatigue 2025-01, Vol.190, p.108657, Article 108657
• Main Authors: Zhou, Chengshuang, Jiang, Changcheng, Jin, Yan, Zhou, Hongbin, Qiu, Qingxiong, Hu, Yuqing, Xie, Yuchen, Zhang, Lin, Zheng, Jinyang
• Format: Article
• Language: English
• Subjects: Fatigue crack growth; Hydrogen embrittlement; Hydrogen transport; Microstructure; Tempering temperature
• ISSN: 0142-1123
• DOI: 10.1016/j.ijfatigue.2024.108657

•550 °C tempered steel has the worst resistance to hydrogen embrittlement.•600 °C tempered steel has the best resistance to hydrogen embrittlement.•Precipitated phase and dislocation density affect HE resistance. In this study, the hydrogen embrittlement behavior of quenched pipeline steel tempered at 550 °C to 650 °C in a high-pressure hydrogen environment was analyzed. Hydrogen permeation tests and microstructural analyses indicated that the dislocation density of the steel decreases with increasing tempering temperature, while precipitates gradually nucleate and grow. These hydrogen traps interact with hydrogen atoms, resulting in significantly higher diffusible hydrogen content in steel tempered at 550 °C compared to that tempered at 600 °C and 650 °C. Fatigue crack growth (FCG) test results show that steel tempered at 600 °C and 650 °C exhibits significantly better hydrogen embrittlement resistance than steel tempered at 550 °C. This is primarily due to the combined effect of the high hydrogen concentration, high dislocation density and low nano carbide content in the steel tempered at 550 °C, which inhibits dislocation slip and emission, leading to high crack tip stress and rapid crack propagation. In contrast, the low dislocation density and and dispersed nano carbides in steel tempered at 600 °C and 650 °C facilitate some dislocation slip and emission, result in crack tip stress relaxation and reduced crack propagation rate. Properly controlling the initial dislocation density and increasing the density of irreversible hydrogen traps can enhance the strength of materials while improving their resistance to hydrogen embrittlement.