Active screen plasma surface co-alloying of 316 austenitic stainless steel with both nitrogen and niobium for the application of bipolar plates in proton exchange membrane fuel cells

• Published in: International journal of hydrogen energy 2015-08, Vol.40 (32), p.10281-10292
• Main Authors: Lin, Kaijie, Li, Xiaoying, Tian, Linhai, Dong, Hanshan
• Format: Article
• Language: English
• Subjects: 316 stainless steel; Active screen plasma surface alloying; Bipolar plates; Niobium; Nitrogen; Proton exchange membrane fuel cells
• ISSN: 0360-3199; 1879-3487
• DOI: 10.1016/j.ijhydene.2015.06.010

Austenitic stainless steel has been researched as a promising candidate material for bipolar plates in proton exchange membrane fuel cells. However, its interfacial contact resistance (ICR) is about 16 times higher that of the Department of Energy (DOE) target (10 mΩ cm2), which leads to undesirable fuel cell performance. In this work, a new hybrid plasma surface engineering process, based on active screen plasma co-alloying, has been developed to simultaneously alloy 316 austenitic stainless steel (316 SS) surfaces with both nitrogen and niobium. The results demonstrated that the layer structure of the modified surfaces can be tailored by adjusting the treatment conditions. All the plasma treated 316 SS samples exhibited significantly reduced ICR below the DOE target of 10 mΩ cm2. The corrosion resistance of the N/Nb co-alloyed 316 SS was much better than active screen plasma nitrided and marginally better than the untreated material. •A new plasma surface process for alloying 316 SS with N and Nb has been developed.•The surface layer structure can be tailored by adjusting the treatment conditions.•The ICR value of 316 SS can be significantly reduced to below the DOE target.