Electrodeposition of Ni–Fe–Mn ternary nanosheets as affordable and efficient electrocatalyst for both hydrogen and oxygen evolution reactions

• Published in: International journal of hydrogen energy 2020-09, Vol.45 (46), p.24670-24683
• Main Authors: Ashraf, Muhammad Aqeel, Li, Cheng, Pham, Binh Thai, Zhang, Dangquan
• Format: Article
• Language: English
• Subjects: Hydrogen evolution reaction; Nanosheets; Oxygen evolution reaction
• ISSN: 0360-3199; 1879-3487
• DOI: 10.1016/j.ijhydene.2020.06.249

The synthesis of high performance and economical electrocatalysts in the process of overall water splitting is very important for the production of hydrogen energy and has become one of the most important challenges. Here, various Ni, Ni–Fe, Ni–Mn nanosheets and Ni–Fe–Mn ternary nanosheets were created using cost-effective, versatile and binder-free electrochemical deposition methods, and the electrocatalytic activity of various electrodes for hydrogen evolution reaction (HER) and oxygen evolution reaction (OER) were investigated in an alkaline environment. Due to the high electrochemical active surface area due to the fabrication of nanosheets, the synergistic effect between different elements on the electronic structure, the high wettability due to the formation of nanosheets and the quick detachment of formed gasses from the electrode, the Ni–Fe–Mn nanosheets electrode showed excellent electrocatalytic activity. In order to deliver the 10 mA cm−2 current density in HER and OER processes, this electrode required values of 64 mV and 230 mV overpotential, respectively. Also, the stability test showed that after 10 h of electrolysis at a current density of 100 mA cm−2, the overpotential changes was very small (less than 4%), indicating that the electrode was excellent electrostatic stability. Also, when using as a bi-functional electrode in the full water splitting system, it only needed a cell voltage of 1528 V to deliver a current of 10 mA cm−2. The results of this study indicate a new strategy for the synthesis of active and stable electrocatalysts. •Ni–Fe, Ni–Mn and Ni–Fe–Mn nanosheets were fabricated by electrodeposition method.•The binder-free Ni–Fe–Mn showed outstanding performance for HER.•Fabricated nanosheets electrode exhibited excellent electrocatalytic stability.•High surface area and synergistic effect of elements lead to excellent activity.•Ni–Fe–Mn electrode require only 1.523 V for 10 mA cm−2 in overall water splitting.