Analysis of copper chlorine electrolysis for large-scale hydrogen production

• Published in: International journal of hydrogen energy 2023-07, Vol.48 (60), p.22720-22733
• Main Authors: El-Emam, Rami S., Zamfirescu, Calin, Gabriel, Kamiel S.
• Format: Article
• Language: English
• Subjects: Cu–Cl; Electrolysis; Nuclear; Pressurized electrolysis; Scale up
• ISSN: 0360-3199; 1879-3487
• DOI: 10.1016/j.ijhydene.2022.09.192

Nuclear hydrogen production is experiencing an unprecedented momentum worldwide, in response to the increasing demand for clean large-scale hydrogen production in line with the outcomes of the UN Conference of the Parties (COP26). A seamless integration of several innovative nuclear designs including Small Modular Reactors with steam Rankine cycle and the cogeneration of Hydrogen using thermochemical water-splitting cycles (e.g., the Cu–Cl cycle) is possible for a complete solution of hydrogen, oxygen, and electric power generation. In this paper, a process and flow sheet for large-scale hydrogen production by CuCl electrolysis at 50 tonnes per day is proposed and analyzed. The scaled-up process and flow sheet is based on lab-scale experience with 50 l/h hydrogen generation. Pressurized Cu–Cl electrolysis and basic electrolysis are reported to support the scaling up parameters, assumptions, and considerations. Based on determined sizing parameters and energy analysis, the Cu–Cl cycle consumes substantially less primary energy (thermal) than water electrolysis, which makes it a serious competitor, despite its obvious higher investment cost in the hardware. •Flow sheet for large scale hydrogen production by CuCl electrolysis is analyzed.•Consideration of pressurized Cu–Cl electrolysis is discussed and analyzed.•Cu–Cl cycle consumes substantially less primary energy than water electrolysis.