Modelling of methane sorption enhanced reforming for blue hydrogen production in an adiabatic fixed bed reactor: unravelling the role of the reactor's thermal behavior

• Published in: International journal of hydrogen energy 2023-08, Vol.48 (68), p.26475-26491
• Main Authors: Mostafa, Abdelrahman, Rapone, Irene, Bosetti, Aldo, Romano, Matteo C., Beretta, Alessandra, Groppi, Gianpiero
• Format: Article
• Language: English
• Subjects: Adiabatic reactor; CO2 capture; Hydrogen production; Modelling; Sorption enhanced reforming
• ISSN: 0360-3199; 1879-3487
• DOI: 10.1016/j.ijhydene.2023.03.357

Methane sorption enhanced reforming (SER) is investigated in this work as a promising route for blue H2 production. A 1-D dynamic heterogeneous model is developed to evaluate the thermal behavior of a fixed bed reactor under adiabatic conditions. The heterogeneous model allows to decouple the feed gas temperature from the initial solid one in order to investigate the behavior of the reforming step in a temperature swing reforming/regeneration process. The effects of the feed gas temperature, the initial bed temperature, and the bed thermal capacity are studied by evaluating the global impact of each parameter through a set of key performance indices (CH4 conversion, H2 yield and purity, carbon capture ratio) calculated as integrals over the duration of the reforming step. The results highlight the minor effect of the initial bed temperature on the process performances showing the potential of minimizing the extent of a cooling step between regeneration and reforming stages. Besides, due to the endothermic nature of the methane sorption enhanced reforming process at high temperatures, thermal energy must be provided to the SER process to achieve high CH4 conversion and high carbon capture ratio. This can be made either in the form of high feed temperature or by utilizing the energy stored in the bed benefiting from the bed thermal capacity. •Dynamic heterogeneous model reveals the thermal behavior of the SER process.•Strategies to cover the energy demand for efficient H2 production are assessed.•SER allows single step production of >95% purity hydrogen with >85% carbon capture rate.•Potential to avoid the cooling step between regeneration and reforming stages is demonstrated.