Evaluation of hydrogen embrittlement susceptibility of underwater laser direct metal deposited 316L stainless steel

• Published in: International journal of hydrogen energy 2024-09, Vol.82, p.858-871
• Main Authors: Wang, Zhandong, Jia, Zhiyuan, Wu, Erke, Chen, Mingzhi, Sun, Guifang, Han, En-Hou
• Format: Article
• Language: English
• Subjects: Additive manufacturing; Austenitic stainless steel; Dislocation slip; Hydrogen embrittlement; Hydrogen-assisted cracking
• ISSN: 0360-3199
• DOI: 10.1016/j.ijhydene.2024.08.003

Underwater laser direct metal deposition (UDMD) shows great application potential in underwater high-performance repair. The susceptibility of underwater repaired components to hydrogen embrittlement (HE) is not extensively researched yet. In this study, HE in 316L stainless steel repaired by UDMD is systematically investigated and compared with in-air direct metal deposited (DMD) 316L and conventionally manufactured (CM) 316L. The experimental results show that the high cooling rates involved in UDMD contribute to a “austenite-ferrite” solidification mode. The cellular structure with a high-density of dislocations increases the tensile strength of as-built UDMD 316L. Thermal desorption spectroscopy analysis reveals that the hydrogen concentrations are similar for 316L manufactured by three processing methods, suggesting that the complex microstructural features by UDMD and DMD do not provide additional H-trapping sites. SSRT results show that the HE susceptibility is in the sequence: CM 316L (30.7%) > UDMD 316L (15.1%) > DMD 316L (9.6%). Compared with CM 316L, the stable cellular structure and higher stability towards martensitic transformation of as-built 316L are beneficial for the HE resistance. In the hydrogen-charged UDMD 316L, the hydrogen-assisted dislocation movement and mechanical twinning formation enhance the localized plasticity and induce cracking. The micron-sized oxide particles and micro-pores further contribute to the fast decohesion of interfaces in the presence of hydrogen. Those combined effects lead to the reductions in tensile strength and elongation of the hydrogen-charged UDMD 316L. •High cooling rates in UDMD lead to cellular structures with high dislocation density.•Complex microstructures in UDMD 316L do not provide additional H-trapping sites.•HE susceptibility of UDMD 316L is larger than that of in-air DMD 316L.•H-assisted dislocation movement and twinning formation induce cracking of UDMD 316L.•Micron-sized oxide particles and micro-pores with H contribute to premature failure.