Macroscopic and microscopic studies of methylene blue sorption onto extracted celluloses from Posidonia oceanica

• Published in: Industrial crops and products 2013-02, Vol.45, p.106-113
• Main Authors: Douissa, Najoua Ben, Bergaoui, Latifa, Mansouri, Samar, Khiari, Ramzi, Mhenni, Mohamed Farouk
• Format: Article
• Language: English
• Subjects: Adsorption; biomass; Cellulose; electrostatic interactions; Fourier transform infrared spectroscopy; Methylene 25 blue; methylene blue; Posidonia oceanica; scanning electron microscopy; Spectroscopic characterization; titration
• ISSN: 0926-6690; 1872-633X
• DOI: 10.1016/j.indcrop.2012.12.007

► We examine sorption of MB on extracted cellulose from Posidonia oceanica. ► Macroscopic data fit well with a pseudo second order kinetic. ► Equilibrium data agreed well with Langmuir isotherm model. ► Adsorption of MB could be achieved mainly on external fibre surface. ► Electrostatic and hydrogen bonding takes place in the interaction MB-cellulose. This study examined the sorption behavior of methylene 25 blue (MB) on extracted cellulose from Posidonia oceanica; an abundant Mediterranean biomass. Physicochemical characterization of extracted material was performed by Boehm titration, pHZPC determination, Scanning Electron Microscopy (SEM) and spectroscopic analysis (UV–vis, XDR, FTIR and XPS). The pHZPC occurred around pH 3.5. The empirical kinetic data fitted very well the pseudo-second-order kinetic. The isotherm data fitted rightly to the Langmuir isotherm model one with a maximum adsorption capacity of 0.955mmolg−1. It seems that electrostatic interactions play an important role during the MB species adsorption process. The departure of water molecules when samples dry gives away more complex interaction mechanisms between MB species and extracted cellulose surface groups.