Self-Standing vanadium oxide pillared carbon microfiber film as an excellent anode for lithium & sodium ion batteries

• Published in: Inorganic chemistry communications 2024-12, Vol.170, p.113431, Article 113431
• Main Authors: Kale, Sayali B., Chothe, Ujjwala P., Bhattacharjee, Kaustav, Kale, Bharat B., Kulkarni, Milind V., Pavitran, S., Terashima, C., Fujishima, Aakira, Gosavi, Suresh W.
• Format: Article
• Language: English
• Subjects: CMFs; Dilute GICs; Electrospinning; LIBs/SIBs; Molecular doping
• ISSN: 1387-7003
• DOI: 10.1016/j.inoche.2024.113431

[Display omitted] •DFT calculations verified the GIC type 1 model, aligning well with experimental results.•This innovative approach has not been explored in the literature before, marking a significant advancement in the field.•The fabricated anode demonstrates significantly improved rate capability and reversible specific capacity.•The pillars enhance the electrode's structural integrity and electrochemical properties, advancing energy storage. Insertion of substances (such as atoms/molecules/ions) into the interlayer spaces of graphite to increase its layer separation is found to be extremely useful for sodium-ion batteries (SIBs). Therefore, expanded graphitic systems are the obvious choice as anode material for both lithium/sodium-ion batteries (LIBs/SIBs). Hard carbon-based materials altogether give a decent electrochemical performance, as well as allow structural integrity for long-term use. Herein, we report a facile route to prepare free-standing vanadium oxide doped carbon microfibers (V@CMFs) films. The V@CMFs show ∼ 200 % expansion in the graphitic interlayer distances while accommodating minute deformations in the final compound which is further theoretically verified as the stage-1 type dilute graphite intercalation compound (GICs) with pillar-like structures. Best battery performance was obtained for the 1 % doped (V1@CMFs) sample, with an initial discharge capacity of 1501.8 and 703.4 mAhg−1, reversible capacities of 1253.8 and 288.7 mAhg−1 at 20 mAg−1, and rate capabilities i.e., 362.4 and 108.1 mAhg−1 at 1600 mAg−1, for LIBs and SIBs, respectively. The results revealed that the rate capability and the reversible specific capacity of the 1 % vanadium oxide doped carbon microfibers (V1@CMFs) are significantly superior compared to the pristine and previous reports. Here, the incorporation of just 1 % vanadium oxide acts as a pillar, enhancing the stability and conductivity of the carbon. Thus, the present work highlights the utility of molecularly doped GICs as potential anode materials for LIBs/SIBs.