Catalytic coal hydrogasification by cobalt-calcium catalyst in a pressurized fluidized bed: Role of hydropyrolysis and catalysis process

• Published in: Journal of analytical and applied pyrolysis 2018-10, Vol.135, p.251-259
• Main Authors: Yan, Shuai, Zhang, Jianshu, Yan, Xiaoqiang, Pan, Dengfeng, Ren, Hui, Qu, Xuan
• Format: Article
• Language: English
• Subjects: Catalytic hydrogasification; Coal; Hydropyrolysis; Methane
• ISSN: 0165-2370; 1873-250X
• DOI: 10.1016/j.jaap.2018.08.028

•Coal catalytic pyrolysis and hydrogasification was analyzed in a fluidized bed.•Catalytic pyrolysis atmosphere greatly affects subsequent char reactivity.•Catalytic hydropyrolysis yields char with disordered structure and more volatiles.•Union of Co-Ca catalyst and H2 rapidly fracture CC bonds in coal structure.•Catalytic cleavage of CC bonds dominates coal catalytic hydrogasification. Coal pyrolysis, hydropyrolysis and hydrogasification were performed in a lab-scale pressurized fluidized bed with or without cobalt-calcium bimetallic catalyst (Co-Ca) to preliminarily discern the role of hydropyrolysis, Co-Ca catalyst and H2 in the course of coal catalytic hydrogasification (CCHG). The hydrogasification reactivity and chemical structure of the coal chars generated after hydropyrolysis were also analyzed by means of pressurized thermogravimetric analyzer (P-TGA), FT-Raman and FT-IR, etc. Results indicate that Co-Ca catalyst possesses catalytic depolymerization and hydrogenation effect on coal during hydropyrolysis, which resulted in the promoted yield of CH4, tar and the high hydrogasification reactivity of the generated char. Co-Ca catalyst alone and H2 alone are hardly to fracture the CC bonds in condensed aromatic rings of coal, but the union of them yields a superior bonds cleavage ability. The catalytic cleavage of CC bonds is the crucial step of CCHG at the temperature above 800 °C with the hydrogen pressure above 1 MPa. Moreover, the CCHG process over Co-Ca catalyst is discussed and the probable pathways of the catalytic cleavage of CC bonds are proposed.