Zinc-catalyzed ester bond cleavage: Chemical degradation of polyethylene terephthalate

• Published in: Journal of cleaner production 2019-01, Vol.208, p.1469-1475
• Main Authors: Wang, Yuqi, Zhang, Yao, Song, Hongyan, Wang, Yingxiong, Deng, Tiansheng, Hou, Xianglin
• Format: Article
• Language: English
• Subjects: Chemical recycling; Controlled degradation; Coordination catalysis; Polyethylene terephthalate; Selective cleavage
• ISSN: 0959-6526; 1879-1786
• DOI: 10.1016/j.jclepro.2018.10.117

Polyethylene terephthalate (PET) materials were recycled by physical methods for a long time. Chemical degradation and recycling of PET materials draw more and more attention in recent years. In this work, PET materials were degraded and recycled via selective cleavage of ester bonds using ZnCl2 as catalysts in aqueous solution. Degradation system 70% ZnCl2/H2O presented excellent catalytic properties due to the coordination catalysis of Zn2+. Monomers terephthalic acid (TPA) was reclaimed at 180 °C for 8 h. The yield of TPA reached up to 98.31%, and the purity of TPA was up to 97.14%. The degradation system ZnCl2/H2O solution was recycled and reused for 3 times, and the degradation ratio of PET materials was still up to 100%. In the degradation process, no organic solvent was added. The work provides a green and sustainable strategy to recover high-value-added chemicals (TPA) from waste PET materials in aqueous phase. Chemical degradation of polyethylene terephthalate was developed to produce terephthalic acid and ethylene glycol via selective cleavage of ester bonds. [Display omitted] •Chemical degradation of PET material was achieved via selective cleavage of ester bonds.•The coordination catalysis of Zn2+ accelerated the hydrolysis process of ester bonds.•High value-added chemicals were recovered from waste PET materials.