Thermodynamics of fuels with a bio-synthetic component (IV): (Vapor + liquid) equilibrium data for the ternary mixture (ethyl 1,1-dimethylethyl ether + 1-hexene + toluene) at T = 313.15 K

The paper reports experimental p– x data for the ternary system (ethyl 1,1-dimethylethyl ether + 1-hexene + toluene) at T = 313.15 K. The ether, synthesized from ethanol of biological origin, increases the interest of this compound as an additive for gasolines. An isothermal total pressure cell was...

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Bibliographic Details
Published in:The Journal of chemical thermodynamics 2009-02, Vol.41 (2), p.189-192
Main Authors: Villamañán, Rosa M., Segovia, José J., Carmen Martín, M., Vega-Maza, David, Chamorro, César R., Villamañán, Miguel A.
Format: Article
Language:English
Subjects:
1-Hexene
Chemistry
ETBE
Exact sciences and technology
General and physical chemistry
Liquid-vapor equilibria
Phase equilibria
Toluene
VLE
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Summary:The paper reports experimental p– x data for the ternary system (ethyl 1,1-dimethylethyl ether + 1-hexene + toluene) at T = 313.15 K. The ether, synthesized from ethanol of biological origin, increases the interest of this compound as an additive for gasolines. An isothermal total pressure cell was used for the measurements. Data reduction by Barker’s method provides correlations for G E, using Wilson, NRTL, UNIQUAC models and the Wohl expansion for the ternary system and the calculation of the vapor phase composition. Good results are obtained for the correlation by all the models.
ISSN:0021-9614
1096-3626
DOI:10.1016/j.jct.2008.09.020