Characterization by differential scanning calorimetry of thermal storage properties of organic PCMs with operating temperature of 150 °C

• Published in: The Journal of chemical thermodynamics 2023-11, Vol.186, p.107136, Article 107136
• Main Authors: Fatahi, Hazhir, Claverie, Jérôme P., Poncet, Sébastien
• Format: Article
• Language: English
• Subjects: Differential scanning calorimetry; Enthalpy; Heat capacity; Melting point; Phase change materials; Thermal energy storage
• ISSN: 0021-9614; 1096-3626
• DOI: 10.1016/j.jct.2023.107136

•Thermal properties of three organic PCMs is investigated by DSC for energy storage.•Enthalpy-Temperature plots of the PCMs are presented.•Effect of sample mass and heating rate on transition temperature range is determined.•Thermal stability of the PCMs is observed during 150 thermal cycles. The involvement of Phase Change Materials (PCMs) in energy storage systems leads to more sustainable and efficient use of energy. Medium operating temperature (melting point 100–400 °C) find various applications in industrial waste heat recovery and hybrid compressed air - thermal energy storage systems. However, there is still a lack of detailed knowledge in terms of their thermal storage properties that hinders them from being more integrated in industry. In this study, thermal properties such as melting point, enthalpy and heat capacity of three medium temperature PCMs were characterized using Differential Scanning Calorimetry (DSC). The enthalpy-temperature graph for each PCM is presented that contains key information on sensible and latent heat contribution in the total energy storage. The selected organic PCMs are adipic acid with two different purities 99%, 99.5%, and its chemical equivalent PureTemp151® with a melting point of (150.5 ± 0.5 °C) and a latent heat of (230 ± 10 J/g). Furthermore, the effect of heating rate and sample mass in DSC procedures on transition temperatures and enthalpy were evaluated. Finally, thermal performance of PCMs was quantified through 150 cycles of melting and solidification. The tested PCMs show a significant storage capacity and good thermal stability with less than 10 % enthalpy loss.