A 3D conducting scaffold with in-situ grown lithiophilic Ni2P nanoarrays for high stability lithium metal anodes

• Published in: Journal of energy chemistry 2021-03, Vol.54, p.301-309
• Main Authors: Jiang, Huai, Fan, Hailin, Han, Zexun, Hong, Bo, Wu, Feixiang, Zhang, Kai, Zhang, Zhian, Fang, Jing, Lai, Yanqing
• Format: Article
• Language: English
• Subjects: 3D metal framework; Li metal anodes; Ni2P nanoarrays; Superior lithiophilicity; Uniform Li deposition
• ISSN: 2095-4956
• DOI: 10.1016/j.jechem.2020.06.004

A 3D conducting scaffold with in-situ grown lithiophilic Ni2P nanoarrays (PNF) is well-designed via the facile two-step process of hydrothermal-phosphating. Consequently, high stability Li metal anodes (PNF-Li) can be achieved. [Display omitted] Lithium (Li) metal is the most potential anode material for the next-generation high-energy rechargeable batteries. However, intrinsic surface unevenness and ‘hostless’ nature of Li metal induces infinite volume effect and uncontrollable dendrite growth. Herein, we design the in-situ grown lithiophilic Ni2P nanoarrays inside nickel foam (PNF). Uniform Ni2P nanoarrays coating presents a very low nucleation overpotential, which induces the homogeneous Li deposition in the entire spaces of three-dimensional (3D) metal framework. Specifically, the lithiophilic Ni2P nanoarrays possess characteristics of electrical conductivity and structural stability, which have almost no expansion and damage during repeating Li plating/stripping. Therefore, they chronically inhibit the growth of Li dendrites. This results in an outstanding Coulombic efficiency (CE) of 98% at 3 mA cm−2 and an ultralong cycling life over 2000 cycles with a low overpotential. Consequently, the PNF-Li||LiFePO4 battery maintains a capacity retention of 95.3% with a stable CE of 99.9% over 500 cycles at 2C.