Influence of guanidine on kinetics of hydrogen evolution reaction on iron and its diffusion through steel membrane in acidic chloride media

• Published in: Journal of electroanalytical chemistry (Lausanne, Switzerland) Switzerland), 2011-04, Vol.653 (1-2), p.1-6
• Main Authors: Vigdorovich, V.I., Tsygankova, L.E., Balybin, D.V.
• Format: Article
• Language: English
• Subjects: aqueous solutions; carbon; Diffusion; electrodes; ethylene; ethylene glycol; Guanidine; Hydrogen; hydrogen ions; hydrogen production; ionic strength; ions; Iron; Membrane; Solvent; steel; water
• ISSN: 1572-6657; 1873-2569
• DOI: 10.1016/j.jelechem.2011.01.026

► The role of the solvent nature in kinetics of hydrogen evolution reaction (HER) on iron. ► Influence of guanidine on HER kinetics and mechanism. ► Connection between HER mechanism and hydrogen diffusion flux. Connection between kinetics of hydrogen evolution reaction on iron and concentrations of hydrogen ions (at constant ionic strength equal to 1) and guanidine has been studied in the aqueous (hydrogen ions discharge is rate determining stage) and ethylene glycol+water (10wt.% H2O, recombination of adsorbed hydrogen is rate determining stage) acidic chloride solutions. Guanidine (NH2)2CNH is entirely protonated in the studied conditions. But in the aqueous solutions, a rate of its cathode reduction is insignificant and main proton donor is H3O+-ions. In ethylene glycol solutions a rate of guanidine ions discharge is larger, that though does not determine a nature of rate determining stage. Observed regularities are compared with hydrogen diffusion rate iH through the carbon steel membrane. iH value insignificantly depends on guanidine concentration in aqueous media, especially in the range of its small concentrations. In the ethylene glycol media such a dependence is considerable up to 1mM guanidine concentration.. Nature of rate determining stage of hydrogen evolution reaction does not determine a character of iH=f(CHCl) and iH=f(Cguanidine) dependences.