Room temperature enhanced blue–green, yellow–orange and red phosphorescence from some compounds of the type (CH3NH3)n−1(1-naphthylmethyl ammonium)2Pbn(ClxBr1−x)3n+1 (with n=1, 2 and 0≤x≤1) and related observations from similar compounds

• Published in: Journal of luminescence 2014-05, Vol.149, p.287-291
• Main Authors: Papavassiliou, George C., Mousdis, George A., Pagona, Georgia, Karousis, Nikolaos, Vidali, Maria-Sofia
• Format: Article
• Language: English
• Subjects: Condensed matter: electronic structure, electrical, magnetic, and optical properties; Electron states; Enhanced luminescence intensity; Exact sciences and technology; Excitons and related phenomena; Low dimensional systems; Methods of electronic structure calculations; Optical properties and condensed-matter spectroscopy and other interactions of matter with particles and radiation; Organic–inorganic hybrides; Photoluminescence; Physics
• ISSN: 0022-2313; 1872-7883
• DOI: 10.1016/j.jlumin.2014.01.050

The photoluminescence spectra of particulate organic–inorganic hybrid compounds, such as (CH3NH3)(C10H7CH2NH3)2Pb2Cl7, (CH3NH3)(C10H7CH2NH3)2Pb2(Cl0.65Br0.35)7 or (C10H7CH2NH3)2PbBr4 and (C10H7CH2NH3)2PbBr4-water, observed with 350nm excitation, exhibit a blue–green, a yellow–orange and a red phosphorescence band, respectively. The observation of enhanced light emission with a naked eye, even at room temperature, is attributed to the energy transfer from Wannier excitonic levels of inorganic to several states of the organic moiety, namely to the energy levels close to those of dimers, trimers, and tetramers of chromophore moieties. The experimental results are in qualitative agreement with those obtained theoretically by others, applying ab initio calculations. The results were compared with those obtained from 2-naphthylmethyl, 4-phenylbenzyl and 9-pyrenylmethyl analogues. •With 350nm excitation at RT, several phosphorescence bands were observed.•Particulate (CH3NH3)(C10H7CH2NH3)2Pb2Cl7 exhibits a blue–green (BG) emission.•(CH3NH3)(C10H7CH2NH3)2Pb2(Cl0.65Br0.35)7 exhibits a yellow–orange (YO) emission.•(C10H7CH2NH3)2PbBr4-water exhibits a red (R) emission.