Sequential growth controlled copper vanadate nanopebbles embedded thin films: Electrode to asymmetric supercapacitive device assembly

• Published in: The Journal of physics and chemistry of solids 2024-12, Vol.195, p.112286, Article 112286
• Main Authors: Sankapal, Suraj R., Deshmukh, Tushar B., Bagde, Ajinkya G., Patil, Komal, Sankapal, Babasaheb R., Lokhande, Chandrakant D.
• Format: Article
• Language: English
• Subjects: Asymmetric supercapacitor; Chemical method; Copper vanadate oxide; Supercapacitor
• ISSN: 0022-3697
• DOI: 10.1016/j.jpcs.2024.112286

Supercapacitor performance critically relies on the design of electrodes with both superior electrochemical and mechanical properties. In this study, we present a cost-effective and scalable approach for the synthesis of copper vanadate (Cu3V2O8) nanopebbles integrated into a thin film, tailored for supercapacitor applications. The synthesis was accomplished using the successive ionic layer adsorption and reaction (SILAR) method, which enabled precise control over the deposition of Cu3V2O8 on a stainless steel (SS) substrate. Detailed structural, morphological, and elemental characterizations confirm the successful formation and reveal critical insights into the chemical bonding and oxidation state at material. The supercapacitive performance of Cu3V2O8 electrode has been evaluated in an aqueous NaClO4 electrolyte to assess pseudocapacitive behavior. The Cu3V2O8 electrode exhibited a specific capacitance of 443 F g−1 at 5 mV s−1 scan rate. Additionally, liquid configured an asymmetric device was designed using Multiwalled carbon nanotubes (MWCNT) combined with Cu3V2O8, yielding a specific capacitance of 116 F g−1 at 5 mV s−1 with an energy density of 8.43 Wh kg−1 and a power density of 345.4 W kg−1, while maintaining capacitance retention of 76 % even after 4000 cycles as stability test. This work highlights the potential of Cu3V2O8 based materials for excellent performance of new avenues for energy storage. [Display omitted] •The Cu3V2O8 was synthesized using facile SILAR method at various deposition cycles.•The surface morphology of well-covered nanopebbles is grouped to form agglomerates to increase film porosity.•The Cs of 443 F g−1 was achieved for Cu3V2O8 electrode in 1.5 M NaClO4 electrolyte.•The Cu3V2O8/NaClO4/MWCNT ASC device delivered an SE of 8.43 Wh kg−1 at 345.4 W kg−1SP.