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Chalcone derivatives as fluorescence turn-on chemosensors for cyanide anions

Three o-hydroxy chalcone derivatives with carbazolyl (1), pyrene (2) and 4-nitrobenzene (3) as terminal group have been synthesized, which exhibit remarkable response to cyanide anions. Compound 3 can recognize cyanide anions with fluorescence turn-on response in CH3CNH2O (1:1, v/v) solution. [Displ...

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Published in:Journal of photochemistry and photobiology. A, Chemistry. Chemistry., 2012-09, Vol.244, p.65-70
Main Authors: Sun, Yunhui, Chen, Huihui, Cao, Duxia, Liu, Zhiqiang, Chen, Hongyu, Deng, Yunlong, Fang, Qi
Format: Article
Language:English
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Summary:Three o-hydroxy chalcone derivatives with carbazolyl (1), pyrene (2) and 4-nitrobenzene (3) as terminal group have been synthesized, which exhibit remarkable response to cyanide anions. Compound 3 can recognize cyanide anions with fluorescence turn-on response in CH3CNH2O (1:1, v/v) solution. [Display omitted] ► Three o-hydroxy chalcone derivatives were synthesized. ► The compounds can recognize cyanide anions with fluorescence turn-on response. ► The compound containing nitro group can recognize cyanides in aqueous solution. Three o-hydroxy chalcone derivatives 1–3 with carbazolyl (1), pyrene (2) and 4-nitrobenzene (3) as terminal group have been synthesized. Their crystal structures, photophysical properties in CH3CN and recognition properties for cyanide anions have also been examined. The research indicates that the stronger electroaffinity of the chalcone derivative's β-unit is beneficial to Michael reaction and can improve the response rate of the compound to cyanide anions. These compounds are found to be able to recognize cyanide anions with fluorescence turn-on response. Especially, compound 3 with strong electron accepting group exhibits remarkable response to cyanide anions in CH3CNH2O (1:1, v/v) solution with a ca. 40-fold intensity enhancement.
ISSN:1010-6030
1873-2666
DOI:10.1016/j.jphotochem.2012.06.012