High performance nano-Ni/Graphite electrode for electro-oxidation in direct alkaline ethanol fuel cells

• Published in: Journal of power sources 2016-09, Vol.325, p.653-663
• Main Authors: Soliman, Ahmed B., Abdel-Samad, Hesham S., Abdel Rehim, Sayed S., Ahmed, Mohamed A., Hassan, Hamdy H.
• Format: Article
• Language: English
• Subjects: Electrocatalyst; Electrodeposition-fuel cells; eQCM; Ethanol electrooxidation; FE-SEM
• ISSN: 0378-7753; 1873-2755
• DOI: 10.1016/j.jpowsour.2016.06.088

Ni/Graphite electrocatalysts (Ni/G) are successfully prepared through electrodeposition of Ni from acidic (pH = 0.8) and feebly acidic (pH = 5.5) aqueous Ni (II) baths. The efficiencies of such electrodes are investigated as anodes for direct alkaline ethanol fuel cells through their ethanol electrooxidation cyclic voltammetric (CV) response in alkaline medium. A direct proportionality between the amount of the electrodeposited Ni and its CV response is found. The amounts of the deposited Ni from the two baths are recorded using the Electrochemical Quartz Crystal Microbalance (eQCM). The Ni/G electrodes prepared from the feebly acidic bath show a higher electrocatalytic response than those prepared from the acidic bath. Surface morphology of the Ni particles electrodeposited from feebly acidic bath appears in a nano-scale dimension. Various electrochemical experiments are conducted to confirm that the Ni/G ethanol electrooxidation CV response greatly depends on the pH rather than nickel ion concentration of the deposition bath. The eQCM technique is used to detect the crystalline phases of nickel as α-Ni(OH)2/γ-NiOOH and β-Ni(OH)2/β-NiOOH and their in-situ inter-transformations during the potentiodynamic polarization. •Simple and cheap fabrication of highly efficient nano-Ni/graphite electrocatalyst.•More efficient electrodes for EtOH oxidation were prepared from feebly acidic bath.•Electrode orientation shows attractive effect on its CV response stability.•Nickel hydroxide/oxyhydroxide phase changes detection by eQCM technique.