Electrochemical reaction mechanisms under various charge-discharge operating conditions for Li1.2Ni0.13Mn0.54Co0.13O2 in a lithium-ion battery

• Published in: Journal of solid state chemistry 2018-06, Vol.262, p.294-300
• Main Authors: Konishi, Hiroaki, Hirano, Tatsumi, Takamatsu, Daiko, Gunji, Akira, Feng, Xiaoliang, Furutsuki, Sho, Okumura, Takefumi, Terada, Shohei, Tamura, Kazuhisa
• Format: Article
• Language: English
• Subjects: Cathode; In situ XRD; Lithium-ion battery; Lithium-rich; Open-circuit potential; XAFS
• ISSN: 0022-4596; 1095-726X
• DOI: 10.1016/j.jssc.2018.03.028

The potential in each state of charge (SOC) during charging of Li1.2Ni0.13Mn0.54Co0.13O2 is higher than that during discharging. In other words, the potential hysteresis occurs between charging and discharging. Furthermore, the potential in each SOC changes according to the charge-discharge operating conditions, indicating that the charge-discharge reaction mechanism is also affected. To clarify the effect of charge-discharge operating conditions on the electrochemical reaction, Li1.2Ni0.13Mn0.54Co0.13O2 was charged and discharged under various charge-discharge operating ranges, and open-circuit potential (OCP), crystal structure, and oxidation states of the transition metals were evaluated by electrochemical measurement, X-ray diffraction (XRD), and X-ray absorption fine structure (XAFS). These results indicate that OCP, lattice parameters, and oxidation states of the transition metals of Li1.2Ni0.13Mn0.54Co0.13O2 in each SOC are not constant. The XRD results indicate that two phases, namely, LiNi0.33Mn0.33Co0.33O2-like and Li2MnO3-like, exist in Li1.2Ni0.13Mn0.54Co0.13O2. For the LiNi0.33Mn0.33Co0.33O2-like phase, the relationship between OCP, lattice parameters, and oxidation states of the transition metals in each SOC is not affected by the charge-discharge operating conditions, indicating that extraction and insertion of lithium ions for the LiNi0.33Mn0.33Co0.33O2-like phase progresses at almost the same potential. Although the extraction and insertion of lithium ions for the Li2MnO3-like phase progresses at almost the same potential in the low-SOC region, the OCP and lattice parameter in each SOC in the high-SOC region are not constant. Therefore, the extraction of lithium ions from the Li2MnO3-like phase in the high-SOC region causes the potential hysteresis of Li1.2Ni0.13Mn0.54Co0.13O2. Figure shows the open-circuit potential of Li1.2Ni0.13Mn0.54Co0.13O2 under various charge-discharge operating conditions. As charge-discharge operating range increases, the difference between the potentials for charging and discharging increases. This indicates that the charge-discharge reaction mechanism is also affected by the charge-discharge operating range. [Display omitted]