Spatial variations in dissolved rare earth element concentrations in the East China Sea water column

• Published in: Marine chemistry 2018-09, Vol.205, p.1-15
• Main Authors: Luong, Le Duc, Shinjo, Ryuichi, Hoang, Nguyen, Shakirov, Renat B., Syrbu, Nadezhda
• Format: Article
• Language: English
• Subjects: East China Sea; Kuroshio current; Okinawa trough; Rare earth element; Seawater
• ISSN: 0304-4203; 1872-7581
• DOI: 10.1016/j.marchem.2018.07.004

A set of 72 low-volume seawater samples (25 mL) collected from 9 stations in the East China Sea in 2009 and 2011 is analyzed for dissolved rare earth element (REE) concentrations. The elemental concentrations in continental shelf waters are markedly higher than those from the shelf slope and Okinawa Trough waters. The transition in the REE concentrations of seawater between the slope and trough is relatively smooth. In the continental shelf, the influences of fluvial input, e.g., from Changjiang River and Yellow River water, and particle scavenging processes on shelf water are significant. The further northern seawater mass in the Okinawa Trough is likely to be more influenced by fluvial input and coastal water masses from the southern Kyushu at the surface then to interact with deep Kuroshio Current water. The Kuroshio Current, along with the vertical geochemical processes, mainly governs the water in the Okinawa Trough. The North Pacific Deep Water (NPDW)-normalized REE patterns of surface and tropical seawaters from the Okinawa Trough, however, exhibit spatial variation from south to north. The intermediate water of the Okinawa Trough is significantly governed by scavenging processes and REE released from lateral transport from the slope along with the movement of the Kuroshio Current. Some sites are also influenced by hydrothermal venting. The interactions between the Kuroshio Current and shelf water masses are also observed, with pronounced evidence of a “turbidity tongue” intrusion from the shelf to the Kuroshio Current and upwelling of the Kuroshio Current to shelf water. •There is distinct spatial variation of dissolved REEs in the East China Sea.•The shelf waters are characterized by MREEs enrichments.•The REE distribution demonstrates intrusion of East China Shelf seawater into the Kuroshio Current.•The REE patterns in the Kuroshio Current surface and tropical water are different from those in intermediate depth water.