Mass transfer study of phenolic compound liquid-liquid extraction process from bio-oil of coffee shell pyrolysis product

• Published in: Materials today : proceedings 2023-03
• Main Authors: Selvia Fardhyanti, Dewi, Kadarwati, Sri, Hadiyanto, Fatriasari, Widya, Prasetiawan, Haniif
• Format: Article
• Language: English
• Subjects: Coffee shell; Extraction; Mass transfer; Modelling; Pyrolysis
• ISSN: 2214-7853; 2214-7853
• DOI: 10.1016/j.matpr.2023.03.080

Coffee shells are one of the potential renewable materials used in the pyrolysis process to produce bio-oil. However, the amount of phenolic compounds, which is roughly 36.74%, is one of the primary drawbacks of using coffee shell bio-oil as a fuel source. Only a little amount of research has been done on the mass transfer modeling and phenomena of phenol extraction from coffee shell bio-oil. The objectives of this study are to identify the best extraction circumstances, ascertain the empirical correlation of total mass transfer, and produce the empirical correlation of Sherwood number, which can be used to characterize the role of variables in this mass transfer process. The ratio of impeller diameter to tank diameter and the Sherwood number, as well as Reynolds, Schmidt, Weber, dispersed phase holdup, were studied as dimensionless numbers. This study used liquid–liquid extraction process at the temperature of 50 ℃, with chloroform–methanol 80% as a solvent with ratio of 2:1 v/v and use bio-oil to solvent ratio of 1:1 v/v. The extraction time has an interval of 30 min (20, 50, 80, 110 min), with varied impeller diameter (3.5 cm and 4 cm), vessels diameter (9 cm and 10 cm) and mixing speed (250 rpm, 300 rpm, 350 rpm). According to the findings, the greatest phenol yield was obtained at impeller diameter 3.5 cm, tank diameter 9 cm, and mixing speed 300 rpm, with a distribution coefficient of 0.848. The results demonstrate that the maximum overall mass transfer coefficient is 4.096 × 10-4 m/s and that the liquid diffusivity is 1.7965 × 10-9 m2/s. The equation model from this study could be applied to a liquid–liquid extraction process that is scaled up to extract more phenolic compounds from the the produced bio-oil.