On the nature of heavy metals in PM10 for an urban desert city in the Middle East: Shiraz, Iran

• Published in: Microchemical journal 2020-05, Vol.154, p.104596, Article 104596
• Main Authors: Parvizimehr, Ali, Baghani, Abbas Norouzian, Hoseini, Mohammad, Sorooshian, Armin, Cuevas-Robles, Alberto, Fararouei, Mohammad, Dehghani, Mansooreh, Delikhoon, Mahdieh, Barkhordari, Abdullah, Shahsavani, Samaneh, Badeenezhad, Ahmad
• Format: Article
• Language: English
• Subjects: Air pollution; Health risk assessment; Heavy Metals; Iran; PM10; Shiraz
• ISSN: 0026-265X; 1095-9149
• DOI: 10.1016/j.microc.2020.104596

•HMs associated with PM10 were measured in ambient air of Shiraz, Iran.•The major source of HMs associated with PM10 was traffic emissions.•The concentration of HMs had the following order: Fe > Al > Zn > Pb > Cr > Ni > Cd.•LTCR for Cr for children was 1.20 × 10−2, which exceeds the proposed value by EPA.•Children usually had more exposure than adults to HMs associated with PM10. This study investigated the concentrations of suspended particulate matter £ 10 µm in diameter (PM10) and their heavy metal content, including cadmium, lead, chromium, zinc, nickel, aluminum, and iron, in ambient air in the Middle East: Shiraz, Iran. The Crystal Ball 7.3 software package was used to assess carcinogenic and non-carcinogenic health effects due to heavy metal exposure. The mean concentrations of heavy metals increased in the following order: Fe > Al > Zn > Pb > Cr > Ni > Cd. Meanwhile, the average concentrations of PM10 decreased during the same time frame. When comparing PM10 on various days of the week in Iran, including holidays (Thursday and Friday), two days after holidays (Saturday and Sunday), and other days (Monday, Tuesday and Wednesday), the concentrations were higher two days after the holidays as compared to other days of the week (p < 0.05). The excess lifetime cancer risk (ELCR) for Cr, especially for children was 1.20 × 10−2, which surpassed suggested EPA levels. The non-carcinogenic values of heavy metals for children were significantly higher than those for adults for three pathways. The results indicate that children usually had more exposure to heavy metals associated with PM10 as compared to adults.