Nanofiber-coated quartz crystal microbalance with chitosan overlay for highly sensitive room temperature ammonia gas sensor

• Published in: Microchemical journal 2024-11, Vol.206, p.111532, Article 111532
• Main Authors: Katriani, Laila, Aflaha, Rizky, As’ari, Ahmad Hasan, Nurwantoro, Pekik, Roto, Roto, Triyana, Kuwat
• Format: Article
• Language: English
• Subjects: Ammonia; Chitosan; Nanofiber; PVAc; QCM
• ISSN: 0026-265X
• DOI: 10.1016/j.microc.2024.111532

[Display omitted] •Chitosan overlaid-QCM sensor has been employed for ammonia gas sensing.•Chitosan overlay to nanofiber can increase sensor sensitivity and selectivity.•The concentration of chitosan is directly proportional to sensor sensitivity.•The sensor has rapid response, reversible, repeatable, and long-term stability.•Lewis acid-base and dipole–dipole interaction responsible for the sensing mechanism. Ammonia is toxic and can pose health risks. Ensuring the safety of individuals working with or around ammonia sensors is crucial, adding complexity to the design and use of such sensors. An ammonia gas sensor by quartz crystal microbalance coated with chitosan-overlaid polyvinyl acetate (PVAc) nanofiber has been studied to have high performance in both sensitivity and selectivity. The scanning electron microscope (SEM) and Fourier-transform infrared (FTIR) spectroscopy were used to analyze the sensing surface, which was the electrospun PVAc nanofiber with chitosan overlay. The nanofiber showed a morphological change and had a more active layer after being overlaid by chitosan. The estimation of PVAc nanofiber thickness on the QCM sensor is (12.0 ± 2.1) µm, measured using a digital microscope. The QCM sensor deposited with PVAc nanofiber only had a sensitivity of 0.076 Hz·ppm−1. It improved to 3.012 Hz·ppm−1 after overlaid with 0.7 wt% chitosan (denoted as PVAc/Ch7 sensor), an increase of 39.6 times. Moreover, the PVAc/Ch7 sensor had a rapid response and recovery times of 9 and 35 s with a very low detection limit of 0.526 ppm. The sensor also exhibited good selectivity toward other analytes. In addition, the sensor also had outstanding in other performances, such as linearity, repeatability, reversibility, and excellent long-term stability. This proposed QCM-based ammonia sensor could be an alternative to analyzing ammonia in various fields.