Separation of C3/C4 hydrocarbon mixtures by adsorption using a mesoporous iron MOF: MIL-100(Fe)

• Published in: Microporous and mesoporous materials 2012-05, Vol.153, p.178-190
• Main Authors: Plaza, M.G., Ribeiro, A.M., Ferreira, A., Santos, J.C., Hwang, Y.K., Seo, Y.-K., Lee, U.-H., Chang, J.-S., Loureiro, J.M., Rodrigues, A.E.
• Format: Article
• Language: English
• Subjects: Adsorption; C3/C4 separation; Chemistry; Colloidal state and disperse state; Exact sciences and technology; General and physical chemistry; MACADEMIA; Metal Organic Framework; MIL-100(Fe); Porous materials; Surface physical chemistry
• ISSN: 1387-1811; 1873-3093
• DOI: 10.1016/j.micromeso.2011.12.043

Binary propane/isobutane and propylene/isobutane breakthrough curves over MIL-100(Fe) tablets at 150kPa and 373K. [Display omitted] ► MIL-100(Fe) is proposed as a plausible adsorbent for C3/C4 hydrocarbons separation. ► MIL-100(Fe) tablets present a C4/C3 separation factor of 3. ► The results presented (equilibrium data and mathematical model validation) can be used to design PSA processes. In this work an iron MOF, MIL-100(Fe) is proposed as a plausible adsorbent to carry out C3/C4 separation by adsorption. The adsorption equilibrium of pure propane, propylene and isobutane over MIL-100(Fe) was studied by means of a magnetic suspension balance in a wide range of temperature and pressure (323–423K and 0–500kPa). Propane and propylene present nearly linear isotherms at high temperature, while isobutane present steeper isotherms at low pressures, showing higher adsorption capacity than that of propane and propylene in most of the studied range. Multicomponent fixed-bed adsorption experiments confirmed the preferential adsorption of isobutane over propane and propylene, with an adsorption separation factor of 3. A non-isothermal, non-adiabatic, bidisperse mass transfer model that describes satisfactorily the single and multicomponent breakthrough experiments is proposed.