A convenient highly stereoselective synthesis of allyl amides from Baylis–Hillman adducts using Amberlyst-15 as a heterogeneous reusable catalyst

. The Baylis–Hillman adducts have efficiently been converted into the corresponding allyl amides in stereoselective manner by heating in acetonitrile under reflux in the presence of Amberlyst-15 as a catalyst. The catalyst works under heterogeneous conditions and can be recycled.

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Bibliographic Details
Published in:Journal of molecular catalysis. A, Chemical Chemical, 2006-12, Vol.260 (1), p.32-34
Main Authors: Das, Biswanath, Majhi, Anjoy, Banerjee, Joydeep, Chowdhury, Nikhil
Format: Article
Language:English
Subjects:
Allyl amides
Amberlyst-15
Baylis–Hillman adduct
Catalysis
Chemistry
Exact sciences and technology
General and physical chemistry
Heterogeneous recyclable catalyst
Stereoselectivity
Theory of reactions, general kinetics. Catalysis. Nomenclature, chemical documentation, computer chemistry
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Description
Summary:. The Baylis–Hillman adducts have efficiently been converted into the corresponding allyl amides in stereoselective manner by heating in acetonitrile under reflux in the presence of Amberlyst-15 as a catalyst. The catalyst works under heterogeneous conditions and can be recycled.
ISSN:1381-1169
1873-314X
DOI:10.1016/j.molcata.2006.06.051