A mixed solvent system of amino crown ether and ionic liquids for a high-efficient extraction of cesium

• Published in: Journal of molecular liquids 2024-10, Vol.412, p.125868, Article 125868
• Main Authors: He, Jintao, Hua, Junyuan, Ma, Xiaohua, Wickramasinghe, Ranil, Li, Jianxin
• Format: Article
• Language: English
• Subjects: Cesium recovery; Diamino dibenzo-18-crown-6; Hydrogen bond interactions; Ionic liquids; Liquid-liquid extraction
• ISSN: 0167-7322
• DOI: 10.1016/j.molliq.2024.125868

[Display omitted] •A DAB18C6-ILs mixed system was synthesized for a high-efficient extraction of Cs+.•The system displayed a high %ECs (99.94 %), βCs/K (1216.7) and βCs/Rb (139.03).•A high stability of the mixed system is ascribed to the hydrogen bond interaction.•The complex of DAB18C6 with Cs+ showed a low hydration binding energy and high selectivity.•DAB18C6-Cs+-[NTF2]− as the most stable structure formed is based on cation exchange. Efficient extraction of Cs+ from aqueous solution was investigated by liquid–liquid extraction based on ionic liquids (ILs). In this study, Di(aminobenzo)-18-crown-6 (DAB18C6) was used as the extractant and three ILs (1-butyl-3-methylimidazolium hexafluorophosphate ([C4mim][PF6]), 1-hexyl-3-methylimidazolium hexafluorophosphate ([C6mim][PF6]), and 1-butyl-3-methylimidazolium bis-trifluoromethyl sulfonamide ([C4mim][NTf2])) were employed as co-extractants in the construction of a liquid–liquid extraction system for efficient and selective extraction of Cs+ from aqueous solutions. It was demonstrated that the DAB18C6-[C4mim][NTf2] mixed solvent system at 0.12 mol/L DAB18C6, a mass ratio of ILs/CHCl3 of 1:4 and a volumetric ratio of O/A of 1:1 exhibited a high % extraction of Cs+ up to 99.94 %, with a higher selectivity for Cs+ relative to coexisting ions such as K+ (βCs/K = 1216.7) and Rb+ (βCs/Rb = 139.03). The high selectivity of the extraction system for Cs+ was attributed to the lower hydration binding energy of Cs+ (−366.51 kJ/mol) and the stronger interaction between DAB18C6 and Cs+, g(r) = 12.7. Further, the hydrogen bonding interaction between the amino crown ether and ionic liquid increases the viscosity and surface tension of the extraction system, thus enhancing the stability of the system. Noteworthy, the most stable structure formed by DAB18C6-Cs+-[NTF2]− is attributed to cation exchange. In summary, this study demonstrates the great potential for efficient separation and extraction of cesium from aqueous solutions.