Synthesis of Zn2+:LaMnO3 perovskites nanoparticles by facile co-precipitation approach: Physicochemical characteristics and supercapacitor application

• Published in: Materials science & engineering. B, Solid-state materials for advanced technology Solid-state materials for advanced technology, 2024-10, Vol.308, p.117617, Article 117617
• Main Authors: Ambujam, K., Sridevi, A., Pandiaraj, Saravanan, Alodhayb, Abdullah N.
• Format: Article
• Language: English
• Subjects: Co-precipitation; Energy storage device; Nanoparticles; Perovskite crystals; Transition metal doped
• ISSN: 0921-5107
• DOI: 10.1016/j.mseb.2024.117617

[Display omitted] •Zn2+:LaMnO3 perovskites nanoparticles tailored for improved electrochemical performance.•At 1 A g−1 current density, Zn2+:LaMnO3 boost a specific capacitance of 598F g−1.•Zn2+:LaMnO3 perovskites nanoparticles serve as excellent electrode material for supercapacitor applications. This work has examined the impact of Zn2+ on the crystal architecture and electrochemical functionality of LaMnO3 perovskite nanoparticles. Crystalline parameters of the as-prepared samples were analyzed by X-ray Diffraction studies (XRD). Fourier transform infrared (FT-IR) measurements are utilized to detect the functional groups present in the sample. Raman spectroscopy technique was used to analyze the nature of the chemical bonds in the prepared material. The shape and elemental content of the produced nanomaterials were determined using scanning electron microscopy (SEM) and energy dispersive X-ray spectroscopy (EDAX). Brunauer-Emmett-Teller (BET) technique is used to study the porosity and surface area of the material. Electrochemical impedance spectroscopy (EIS), cyclic voltammetry (CV), and galvanostatic charge/discharge (GCD) is employed to study the surface resistivity, oxidation–reduction potential and super capacitance efficiency of the prepared electrode material.