CuS films grown by a chemical bath deposition process with amino acids as complexing agents

• Published in: Materials science in semiconductor processing 2019-01, Vol.89, p.18-25
• Main Authors: Ortiz-Ramos, Daniela E., Martínez-Enríquez, Arturo I., González, Luis A.
• Format: Article
• Language: English
• Subjects: Amino acids; Ammonia-free; Chemical bath deposition; CuS thin films; Electrical properties; Optical properties
• ISSN: 1369-8001; 1873-4081
• DOI: 10.1016/j.mssp.2018.08.016

CuS thin films were deposited by an ammonia-free chemical bath deposition process. This approach uses amino acids (alanine, glycine and serine) as complexing agents. The conditions under which amino acids form complexes and release Cu ions are discussed. All the resulting CuS films, formed by nanoflake particles, had the hexagonal crystalline structure (covellite). Moreover, the coexistence of Cu+ and Cu2+ states in these films were confirmed by X-ray photoelectron spectroscopy. Amino acids as complexing agents were then observed to affect mainly to the growth kinetics of the CuS films. Thus, thicknesses of 42, 55.4 and 70 nm were obtained for the films processed with solution reactions containing alanine, glycine and serine, respectively. The optical band gaps of the films with moderate transmittance had values in the range from 2.25 to 2.4 eV. Finally, the resulting CuS films with electrical resistivities from 1.84 × 10−3 to 2.8 × 10−3 Ω-cm showed a decrease of photosensitivity with the film thickness.