Versatility of hydrophilic and antifouling PVDF ultrafiltration membranes tailored with polyhexanide coated copper oxide nanoparticles

• Published in: Polymer testing 2020-04, Vol.84, p.106367, Article 106367
• Main Authors: Sri Abirami Saraswathi, Meenakshi Sundaram, Rana, Dipak, Divya, Kumar, Gowrishankar, Shanmugaraj, Nagendran, Alagumalai
• Format: Article
• Language: English
• Subjects: Antibiofouling; Hydrophilicity; Poly(vinylidene fluoride); Polyhexanide coated copper oxide; Ultrafiltration membrane
• ISSN: 0142-9418; 1873-2348
• DOI: 10.1016/j.polymertesting.2020.106367

Hydrophilic poly(vinylidene fluoride) (PVDF) nanocomposite ultrafiltration (UF) membranes with excellent antifouling and antibiofouling characteristics are fabricated by employing polyhexanide coated copper oxide nanoparticles (P–CuO NPs). The presence of P–CuO NPs is played a significant role in altering the PVDF membrane matrix and probed by XRD, FTIR, FESEM and contact angle analysis. The PVDF/P–CuO nanocomposite membranes exhibited an outstanding antifouling performance indicated by the superior pure water flux, effective foulant separation and maximum flux recovery ratio during UF experiments as a result of the formation of the hydrophilic and more porous membrane due to the uniform distribution of P–CuO NPs. Particularly, the PVDF/P–CuO-3 membrane showed higher PWF of 152.5 ± 2.4 lm−2h−1 and porosity of 64.5% whereas the lower contact angle of 52.5°. Further, it showed the higher rejection of 99.5 and 98.4% and the flux recovery ratio of 99.5 and 98.5% respectively for BSA and HA foulants, demonstrated its increased water permeation, foulant separation and antifouling behavior. Further, the decent antibacterial activity is showed by the PVDF/P–CuO nanocomposite membranes with the formation of halo-zone around the membrane when exposed to the bacterial medium demonstrated that, by this process an antibacterial water treatment membrane can be developed by simple phase inversion technique with good membrane stability. [Display omitted] •Successful fabrication of PVDF/P–CuO nanocomposite UF membranes.•PVDF/P–CuO membranes showed superior hydrophilicity and water permeation.•PVDF/P–CuO membranes exhibited higher BSA/HA rejection and flux recovery ratio.•PVDF/P–CuO membranes displayed both anti-organic fouling and anti-biofouling.•PVDF/P–CuO membranes are promising for potential use in the water treatment.