Carbon-coating-increased working voltage and energy density towards an advanced Na3V2(PO4)2F3@C cathode in sodium-ion batteries

• Published in: Science bulletin (Beijing) 2020-05, Vol.65 (9), p.702-710
• Main Authors: Gu, Zhen-Yi, Guo, Jin-Zhi, Sun, Zhong-Hui, Zhao, Xin-Xin, Li, Wen-Hao, Yang, Xu, Liang, Hao-Jie, Zhao, Chen-De, Wu, Xing-Long
• Format: Article
• Language: English
• Subjects: Cathode; In-situ XRD; Na3V2(PO4)2F3; Sodium-ion batteries; Working voltage
• ISSN: 2095-9273
• DOI: 10.1016/j.scib.2020.01.018

An advanced Na3V2(PO4)2F3@C cathode material is prepared successfully and exhibits outstanding energy storage performance in sodium-ion batteries. It is for the first time found that the carbon coating can adjust the dis-/charging plateaux to increase the mean voltage (from 3.59 to 3.71 V) and energy density (from 336.0 to 428.5 Wh kg−1) of phosphate cathode material. The enhancement reasons are also elucidated via a serious of comparison studies. [Display omitted] One main challenge for phosphate cathodes in sodium-ion batteries (SIBs) is to increase the working voltage and energy density to promote its practicability. Herein, an advanced Na3V2(PO4)2F3@C cathode is prepared successfully for sodium-ion full cells. It is revealed that, carbon coating can not only enhance the electronic conductivity and electrode kinetics of Na3V2(PO4)2F3@C and inhibit the growth of particles (i.e., shorten the Na+-migration path), but also unexpectedly for the first time adjust the dis-/charging plateaux at different voltage ranges to increase the mean voltage (from 3.59 to 3.71 V) and energy density (from 336.0 to 428.5 Wh kg−1) of phosphate cathode material. As a result, when used as cathode for SIBs, the prepared Na3V2(PO4)2F3@C delivers much improved electrochemical properties in terms of larger specifc capacity (115.9 vs. 93.5 mAh g−1), more outstanding high-rate capability (e.g., 87.3 vs. 60.5 mAh g−1 at 10 C), higher energy density, and better cycling performance, compared to pristine Na3V2(PO4)2F3. Reasons for the enhanced electrochemical properties include ionicity enhancement of lattice induced by carbon coating, improved electrode kinetics and electronic conductivity, and high stability of lattice, which is elucidated clearly through the contrastive characterization and electrochemical studies. Moreover, excellent energy-storage performance in sodium-ion full cells further demonstrate the extremely high possibility of Na3V2(PO4)2F3@C cathode for practical applications.