Nanostructured AlOOH – A promising catalyst to reduce energy consumption for amine-based CO2 capture

• Published in: Separation and purification technology 2022-12, Vol.303, p.122232, Article 122232
• Main Authors: Jiang, Cong, Fan, Maohong, Gao, Ge, Jiang, Wufeng, Li, Xiaoshan, Luo, Cong, Zhang, Liqi, Wu, Fan
• Format: Article
• Language: English
• Subjects: Catalytic desorption; CO2 capture; Metal oxyhydroxide; Monoethanolamine; Nanowire
• ISSN: 1383-5866; 1873-3794
• DOI: 10.1016/j.seppur.2022.122232

[Display omitted] •Nanostructured metal oxyhydroxide AlOOH was synthesized for catalytic CO2 capture for the first time.•A simple but precise heat transfer model was created for heat duty assessment.•The use of AlOOH exhibited the best catalytic performance in increasing the CO2 desorption rate and decreasing the energy consumption in comparison with other catalysts reported.•A thorough catalytic mechanism was proposed and preliminarily validated. In order to alleviate the intensive energy demand of amine-based post-combustion carbon capture technology, metal oxyhydroxide AlOOH of nanoscale was synthesized through the hydrothermal method and applied to accelerate the CO2 desorption rate and reduce the regeneration heat duty of aqueous monoethanolamine (MEA) solution for the first time. Results showed that the use of AlOOH could accelerate the desorption rate by up to 560% and increase the desorption amount by 251%. By comparing the performance between AlOOH and Al2O3, it can be found that the presence of extra hydroxyl groups is 20.6% more efficient in catalyzing CO2 desorption. According to a simplified heat transfer model created in this work, AlOOH could reduce the heat duty by 17% with only 0.1 wt% loading, which exhibited the highest performance cost ratio among related literature. In addition, the cyclic stability of AlOOH was confirmed through various characterization methods, including XRD, FT-IR, SEM, and N2 adsorption–desorption. More importantly, a possible catalytic mechanism of AlOOH was discussed and proved where it could change reaction pathways in different CO2 loading regions. This work reveals a promising research direction towards cost-efficient and high-performance metal oxyhydroxide catalysts in the catalytic amine regeneration field to approach the net-zero carbon emission goal.