Amorphous Fe–Mn binary oxides nanoparticles decorating waste bamboo biomass-based monolith for efficient arsenic removal with column adsorption

• Published in: Separation and purification technology 2024-02, Vol.330, p.125426, Article 125426
• Main Authors: Xu, Lina, Shu, Zhu, Sun, Shuxin, Wen, Yuchen, Zhou, Jun
• Format: Article
• Language: English
• Subjects: Amorphous Fe–Mn oxides; Arsenic adsorption; Bamboo biomass; Monolithic adsorbent; Oxidation-adsorption
• ISSN: 1383-5866; 1873-3794
• DOI: 10.1016/j.seppur.2023.125426

[Display omitted] •Amorphous Fe–Mn binary oxide nanoparticles decorated bamboo monolith (Fe–Mn–O/MB) were synthesized.•Fe–Mn–O/MB are highly effective for aqueous As(III) and As(V) removal.•The adsorbent has the dual function of “oxidation (Mn(IV))-adsorption (Fe(III))”.•Surface complexation was the dominant removal mechanism.•Fe–Mn–O/MB reduced As concentration to less than 10 μg L−1 in column system for 1150 BV. The removal of naturally occurring arsenic from aqueous media remains a challenging endeavor for the protection of public health and ecosystems. Herein, we devised a workable fresh-biomass-based monolith adsorbent by in situ generation of amorphous Fe–Mn binary oxides nanoparticles (Fe–Mn–O) on a waste bamboo biomass (MB) via a simple procedure of pre-oxidation plus co-precipitation. In the pre-oxidation process of MB, the surface underwent roughening and the manganese ions permeated deeply inside the biomass, both of which facilitated the loading of Fe–Mn–O (25.06 wt%). As a result, the Fe–Mn–O/MB had outstanding adsorption capacities of 33.41 and 36.88 mg g−1 for As(III) and As(V), respectively. XRD and FTIR analyses show that the amorphous structure of Fe–Mn–O with low-coordinated active centers provides numerous hydroxyl functional groups that enhance arsenic adsorption, moreover, oxidation of As(III) was realized. In different water matrix, the Fe–Mn–O/MB composite exhibited a retention of 87.33 % and 89.53 % of its original adsorption capacity for As(III) and As(V) after five cycles of reuse as well as enabled continuous operation in a fixed-bed system with a bed volume of around 1150. Therefore, this work provides a promising approach for efficient abatement of inorganic arsenic-caused water pollution.