Revealing humidity-enhanced NH3 sensing effect by using resonant microcantilever

• Published in: Sensors and actuators. B, Chemical Chemical, 2018-03, Vol.257, p.488-495
• Main Authors: Liu, Manyi, Guo, Shuanbao, Xu, Pengcheng, Yu, Haitao, Xu, Tao, Zhang, Sen, Li, Xinxin
• Format: Article
• Language: English
• Subjects: Ammonia sensor; Cancer early diagnosis; Environmental protection; Mesoporous silica; Microcantilever
• ISSN: 0925-4005; 1873-3077
• DOI: 10.1016/j.snb.2017.10.179

•Brønsted acidic mesoporous silica nanoparticles are used as mass-type NH3 sensing material.•The limit of detection to NH3 reaches ppb level.•Humidity-enhanced NH3 sensing effect has been observed.•Molecular formula of hydrate NH3 is identified based on the resonant micro-gravimetric sensing data. High performance NH3 sensor is of great importance in various application fields such as environmental protection and early diagnosis of stomach cancer. Herein, carboxyl group functionalized mesoporous silica nanoparticles (C-MSNs) with ultrahigh specific surface area are developed as high performance mass-type sensing material for trace-level NH3 detection. By using inkjet printing technology, C-MSNs material is precisely loaded on our lab-made integrated resonant microcantilever to construct a mass-type gas sensor. Based on the specific acid-base interaction between Brønsted acidic C-MSNs material and basic NH3 molecules, our sensor exhibits satisfactory NH3 sensing performance. The experimentally observed detection limit of our sensor reaches parts per billion (ppb) level. Exposed to NH3 with identical concentration, our sensor outputs a higher response in wet air than that of in dry atmosphere. In real air, hydrate NH3 molecule (i.e. NH3·xH2O) has a larger molecular weight than anhydrous NH3 in absolute dry experimental atmosphere. Therefore, our gravimetric sensor exhibits a higher response in real air. In order to in-depth elucidate the humidity-enhanced sensing effect, the micro-gravimetric sensing data obtained in wet air and in dry experimental environment are compared together. Based on our quantitatively measurement data, the molecular formula of hydrate NH3·xH2O existing in wet air (with 50–80% relative humidity) can be obtained as NH3·2∼2.4H2O.