Nitrogen isotope marker experiments in austenitic stainless steel for identification of trapping/detrapping processes at different temperatures

• Published in: Surface & coatings technology 2023-11, Vol.472, p.129952, Article 129952
• Main Authors: Mändl, Stephan, Gerlach, Jürgen W., Manova, Darina
• Format: Article
• Language: English
• Subjects: Expanded austenite; In-situ XRD; Nitriding of steel; SIMS
• ISSN: 0257-8972; 1879-3347
• DOI: 10.1016/j.surfcoat.2023.129952

Expanded austenite – austenitic stainless steel containing a colossal amount of nitrogen in solid solution – is still some kind of conundrum with the nitrogen atom transport from the surface into the bulk being enhanced for higher nitrogen content. At the same time, atomic ordering due to an enhanced affinity between chromium and nitrogen is observed. Here, nitrogen transport experiments are performed at different temperatures using 14N and 15N as isotopic tracers. The depth distribution of each of these isotopes as well as the total nitrogen content is investigated with time-of-flight secondary ion mass spectrometry (ToF-SIMS) and glow discharge optical emission spectroscopy (GDOES), respectively. In parallel, phase information is obtained using in situ X-ray diffraction (XRD) during nitriding (for time-resolved data) and during sputter depth profiling (for depth-resolved data). During nitriding, no delayed transport of nitrogen, i.e. trapping, is observed for the expanded austenite. However, as soon as CrN precipitates are formed, nitrogen trapping is a dominant factor with an almost perfect correlation between precipitation and trapping. Cluster ion analysis in SIMS confirms this effect with the abundance of Cr2+ ions significantly increased compared to FeCr+ ions in the presence of precipitation. As nitrogen transport and CrN formation occur in parallel at higher temperatures, further experiments to separate the CrN formation at higher temperatures from the nitrogen transport at lower temperatures have been performed. •Nitrogen isotope marker experiments in austenitic stainless steel using in-situ XRD•Trapping is investigated during a continuous nitrogen supply from the surface.•For low temperatures at 370 °C, no trapping was observed.•At 520 °C and beyond, trapping was encountered as soon as CrN was formed.•CrN precipitation strongly correlated with increased Cr2+/FeCr+ cluster ion ratio.