Quantitative high temperature calorimetry on precipitation in steel and nickel alloys

• Published in: Thermochimica acta 2019-07, Vol.677, p.169-179
• Main Authors: Rowolt, Christian, Milkereit, Benjamin, Andreazza, Philipp, Kessler, Olaf
• Format: Article
• Language: English
• Subjects: Differential Scanning Calorimetry (DSC); High temperature DSC; Inconel 718; Precipitation hardening alloys; René 65; X5CrNiCuNb16-4
• ISSN: 0040-6031; 1872-762X
• DOI: 10.1016/j.tca.2019.01.026

•DSC used for solid phase transformation analysis on high temperature metal alloys.•Methodology for reference sample heat capacity adaption developed.•The latter improves the baseline reliability.•Continuous cooling on precipitation hardening steel and two Ni-based superalloys.•In the Ni-based alloys quench induced precipitation causes a large hardening effect. This work presents a method for the in-situ analysis of solid-solid-phase transformations in precipitation hardening alloys at high temperatures (typically 600–1100 °C). It shows that the Differential Scanning Calorimetry (DSC) methodology originally introduced for low temperatures (typically below 600 °C, e. g. Al-alloys) can be successfully adapted for continuous heating and even continuous cooling on high temperature alloys such as martensitic precipitation hardening steel X5CrNiCuNb16-4 (17-4 PH) as well as the Ni-based superalloys, Inconel 718 and René 65. The high temperature DSC Setaram Labsys EVO was used with both continuous heating, as well as continuous cooling, experiments being performed, using rates of 0.01 to 0.3 K/s. One challenge for high temperature DSC analysis is to find an appropriate reference material. Hence different strategies to obtain quantitative data are discussed.