Enantioselective synthesis of martinelline chiral core and its diastereomer using asymmetric tandem Michael–aldol reaction

The martinelline chiral core 3 and its diastereomer were synthesized by using the asymmetric tandem Michael–aldol reaction as the key step from 4-methoxycarbonylanthranilaldehyde and the α,β-unsaturated aldehyde. [Display omitted]

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Bibliographic Details
Published in:Tetrahedron 2008-12, Vol.64 (51), p.11568-11579
Main Authors: Yoshitomi, Yayoi, Arai, Hiromi, Makino, Kazuishi, Hamada, Yasumasa
Format: Article
Language:English
Subjects:
Asymmetric synthesis
Martinellic acid
Martinelline
Organocatalyst
Tandem Michael–aldol reaction
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Description
Summary:The martinelline chiral core 3 and its diastereomer were synthesized by using the asymmetric tandem Michael–aldol reaction as the key step from 4-methoxycarbonylanthranilaldehyde and the α,β-unsaturated aldehyde. [Display omitted]
ISSN:0040-4020
1464-5416
DOI:10.1016/j.tet.2008.10.032