Asymmetric syntheses of (−)-methyl shikimate and (−)-5a-carba-β- d-gulopyranose from d-arabinose via Mukaiyama-type intramolecular aldolization

New asymmetric syntheses of (−)-methyl shikimate 1 and (−)-5a-carba-β- d-gulopyranose 11 from d-arabinose through a common route which employed Mukaiyama-type intramolecular aldolization as a key step were described.

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Bibliographic Details
Published in:Tetrahedron: asymmetry 2009-01, Vol.20 (1), p.78-83
Main Authors: Liu, Shi-Ling, Shi, Xiao-Xin, Xu, Yu-Lan, Xu, Wei, Dong, Jing
Format: Article
Language:English
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Summary:New asymmetric syntheses of (−)-methyl shikimate 1 and (−)-5a-carba-β- d-gulopyranose 11 from d-arabinose through a common route which employed Mukaiyama-type intramolecular aldolization as a key step were described.
ISSN:0957-4166
1362-511X
DOI:10.1016/j.tetasy.2008.12.028